Enviar artigo por via de e-mail Cluster [Re3S5(Dppe)3]+ and its oxidation to [Re3S4(SO2)(Dppe)3]+
- Autores: Petrov P.A.1,2, Ryzhikov M.R.1,2, Kuratieva N.V.1,2, Konchenko S.N.1,2
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Afiliações:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Novosibirsk State University
- Edição: Volume 42, Nº 3 (2016)
- Páginas: 196-200
- Seção: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213386
- DOI: https://doi.org/10.1134/S1070328416020056
- ID: 213386
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Resumo
The reaction of cluster [Re3S4(Dppe)3Br3]Br with sodium tert-butyl thiolate affords trinuclear cationic cluster [Re3S5(Dppe)3]Br (I). The oxidation of cluster I with air gives [Re3S4(SO2)(Dppe)3]Cl (II), which is characterized by X-ray diffraction analysis in the form of solvate II · 3.5CH2Cl2 (CIF file CCDC 1401732). The DFT calculations indicate the triplet ground state of the [Re3S5(Dppe)3]+ cation and a significant spin density on the equatorial sulfide ligands, favoring the oxidation of the cluster.
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Sobre autores
P. Petrov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Autor responsável pela correspondência
Email: panah@niic.nsc.ru
Rússia, pr. akademika Lavrentieva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
M. Ryzhikov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: panah@niic.nsc.ru
Rússia, pr. akademika Lavrentieva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
N. Kuratieva
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: panah@niic.nsc.ru
Rússia, pr. akademika Lavrentieva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
S. Konchenko
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Novosibirsk State University
Email: panah@niic.nsc.ru
Rússia, pr. akademika Lavrentieva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
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