Crystal structure and magnetic properties of binuclear copper(II) complex with 2-N-(phenylhydrazono)-3-((ethyl-2-olato)imino)-1-phenyl-1,2,3-butanetrione
- Autores: Popov L.D.1, Levchenkov S.I.2, Shcherbakov I.N.1, Tkachev V.V.3, Shilov G.V.3, Tupolova Y.P.1, Samorodnyaya D.S.1, Ivannikova E.V.1, Lukov V.V.1, Kogan V.A.1
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Afiliações:
- Southern Federal University
- Southern Scientific Center
- Institute of Problems of Chemical Physics
- Edição: Volume 42, Nº 2 (2016)
- Páginas: 81-84
- Seção: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213371
- DOI: https://doi.org/10.1134/S1070328416010024
- ID: 213371
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Resumo
The binuclear copper(II) complex based on azomethine, being a condensation product of 2-aminoethanol with 1-phenyl-1,2,3-butanetrione phenylhydrazone, is structurally characterized (CIF file CCDC 1059996). The structure is compared with the structure of an analog containing the axially coordinated pyridine molecule. The influence of the axial coordination of pyridine on the magnetic exchange interaction is studied by the DFT method in the broken symmetry approach.
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Sobre autores
L. Popov
Southern Federal University
Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104
S. Levchenkov
Southern Scientific Center
Autor responsável pela correspondência
Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don
I. Shcherbakov
Southern Federal University
Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104
V. Tkachev
Institute of Problems of Chemical Physics
Email: s.levchenkov@gmail.com
Rússia, Chernogolovka, Moscow oblast, 142432
G. Shilov
Institute of Problems of Chemical Physics
Email: s.levchenkov@gmail.com
Rússia, Chernogolovka, Moscow oblast, 142432
Yu. Tupolova
Southern Federal University
Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104
D. Samorodnyaya
Southern Federal University
Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104
E. Ivannikova
Southern Federal University
Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104
V. Lukov
Southern Federal University
Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104
V. Kogan
Southern Federal University
Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104
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