Crystal structure and magnetic properties of binuclear copper(II) complex with 2-N-(phenylhydrazono)-3-((ethyl-2-olato)imino)-1-phenyl-1,2,3-butanetrione


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The binuclear copper(II) complex based on azomethine, being a condensation product of 2-aminoethanol with 1-phenyl-1,2,3-butanetrione phenylhydrazone, is structurally characterized (CIF file CCDC 1059996). The structure is compared with the structure of an analog containing the axially coordinated pyridine molecule. The influence of the axial coordination of pyridine on the magnetic exchange interaction is studied by the DFT method in the broken symmetry approach.

Sobre autores

L. Popov

Southern Federal University

Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104

S. Levchenkov

Southern Scientific Center

Autor responsável pela correspondência
Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don

I. Shcherbakov

Southern Federal University

Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104

V. Tkachev

Institute of Problems of Chemical Physics

Email: s.levchenkov@gmail.com
Rússia, Chernogolovka, Moscow oblast, 142432

G. Shilov

Institute of Problems of Chemical Physics

Email: s.levchenkov@gmail.com
Rússia, Chernogolovka, Moscow oblast, 142432

Yu. Tupolova

Southern Federal University

Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104

D. Samorodnyaya

Southern Federal University

Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104

E. Ivannikova

Southern Federal University

Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104

V. Lukov

Southern Federal University

Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104

V. Kogan

Southern Federal University

Email: s.levchenkov@gmail.com
Rússia, Rostov-on-Don, 344104

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