Crystal structure and magnetic properties of binuclear copper(II) complex with 2- N -(phenylhydrazono)-3-((ethyl-2-olato)imino)-1-phenyl-1,2,3-butanetrione

L. D. Popov; S. I. Levchenkov; I. N. Shcherbakov; V. V. Tkachev; G. V. Shilov; Yu. P. Tupolova; D. S. Samorodnyaya; E. V. Ivannikova; V. V. Lukov; V. A. Kogan

doi:10.1134/S1070328416010024

Crystal structure and magnetic properties of binuclear copper(II) complex with 2-N-(phenylhydrazono)-3-((ethyl-2-olato)imino)-1-phenyl-1,2,3-butanetrione

Authors: Popov L.D.¹, Levchenkov S.I.², Shcherbakov I.N.¹, Tkachev V.V.³, Shilov G.V.³, Tupolova Y.P.¹, Samorodnyaya D.S.¹, Ivannikova E.V.¹, Lukov V.V.¹, Kogan V.A.¹
Affiliations:
1. Southern Federal University
2. Southern Scientific Center
3. Institute of Problems of Chemical Physics
Issue: Vol 42, No 2 (2016)
Pages: 81-84
Section: Article
URL: https://journals.rcsi.science/1070-3284/article/view/213371
DOI: https://doi.org/10.1134/S1070328416010024
ID: 213371

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Abstract

The binuclear copper(II) complex based on azomethine, being a condensation product of 2-aminoethanol with 1-phenyl-1,2,3-butanetrione phenylhydrazone, is structurally characterized (CIF file CCDC 1059996). The structure is compared with the structure of an analog containing the axially coordinated pyridine molecule. The influence of the axial coordination of pyridine on the magnetic exchange interaction is studied by the DFT method in the broken symmetry approach.