Syntheses, crystal structures, and properties of two supramolecules based on methoxyphenyl imidazole dicarboxylates


Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Two cobalt(II) and cadmium(II) complexes, [Co(H2DMOPhIDC)2(H2O)2] • 2H2O (H3DMOPhIDC = 2-(3,4-dimethoxyphenyl)-1H-imidazole-4,5-dicarboxylic acid) (I), [Cd(H2MOPhIDC)2-(Phen)] • C2H5OH (H3MOPhIDC = 2-(3-dimethoxyphenyl)-1H-imidazole-4,5-dicarboxylic acid, Phen = 1,10-phenanthroline) (II), have been hydro(solvo)thermally synthesized by employing two kinds of organic ligands, H3DMOPhIDC or H3MOPhIDC, respectively. The molecular structures of I and II have been characterized by IR spectra, elemental analyses and single-crystal X-ray diffraction (CIF files CCDC nos. 935845 (I), 935846 (II)). Both complexes show three-dimensional supramolecular structures supported by intermolecular H-bonds. Furthermore, the thermogravimetric and photoluminescent properties of two complexes have been investigated as well.

Авторлар туралы

Y. Sang

College of Chemistry and Chemical Engineering

Хат алмасуға жауапты Автор.
Email: sangyali0814@126.com
ҚХР, ChifengNeimenggu, 024000

J. Xin

College of Chemistry and Chemical Engineering

Email: sangyali0814@126.com
ҚХР, ChifengNeimenggu, 024000

R. Gao

College of Chemistry and Molecular Engineering

Email: sangyali0814@126.com
ҚХР, ZhengzhouHenan, 450001

Қосымша файлдар

Қосымша файлдар
Әрекет
1. JATS XML

© Pleiades Publishing, Ltd., 2016