Complex [Ag(PPh 3 ) 4 ][2-B 10 H 9 NH 3  · 2DMF]: Synthesis and Structure

A. P. Zhdanov; V. V. Voinova; I. N. Klyukin; G. A. Buzanov; M. S. Grigor’ev; K. Yu. Zhizhin; N. T. Kuznetsov

doi:10.1134/S1070328419080098

Complex [Ag(PPh₃)₄][2-B₁₀H₉NH₃ · 2DMF]: Synthesis and Structure

Authors: Zhdanov A.P.¹, Voinova V.V.¹, Klyukin I.N.¹, Buzanov G.A.¹, Grigor’ev M.S.², Zhizhin K.Y.¹, Kuznetsov N.T.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Issue: Vol 45, No 8 (2019)
Pages: 563-568
Section: Article
URL: https://journals.rcsi.science/1070-3284/article/view/214803
DOI: https://doi.org/10.1134/S1070328419080098
ID: 214803

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Abstract

The formation of complex salt [Ag(PPh₃)₄][2-B₁₀H₉NH₃ ∙ 2DMF] (I) by the reaction of the salts of the [2-B₁₀H₉NH₃]^– anion with [Ag(PPh₃)₄]NO₃ is studied. The anionic moiety of complex I is a stable solvate linked by hydrogen bonds of two types. Compound I is identified by IR spectroscopy and elemental, X-ray structure, and X-ray diffraction analyses (CIF file CCDC no. 1884451).