Email this article Dysprosium Thiocyanate Complexes with s-Triazine
- Authors: Petrosyants S.P.1, Ilyukhin A.B.1, Babeshkin K.A.1, Belova E.V.1,2, Gavrikov A.V.1, Efimov N.N.1
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Moscow State University
- Issue: Vol 45, No 8 (2019)
- Pages: 592-599
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214817
- DOI: https://doi.org/10.1134/S1070328419080062
- ID: 214817
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Abstract
The reaction of Dy(NCS)3 · 6H2O with 2,4,6-tris(2-pyridyl)-s-triazine (Tptz) in МеОН, MeCN, and H2O affords mononuclear neutral and ionic thiocyanate complexes with tridentate ligand Tptz: [Dy(H2O)(MeOH)(Tptz)(NCS)3] · Tptz (I), [Dy(Tptz)2(NCS)3] · MeCN (II), and [Dy(H2O)3-(Tptz)(NCS)2] · NCS · Tptz · 1.5H2O · 1.25MeOH (III). Structural features of the synthesized compounds are determined using powder XRD, IR spectroscopy, and thermoanalytical methods (thermogravimetry and differential scanning calorimetry). Compounds II and III exhibit the properties of single-molecule magnets.
About the authors
S. P. Petrosyants
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: petros@igic.ras.ru
Russian Federation, Moscow, 119991
A. B. Ilyukhin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: petros@igic.ras.ru
Russian Federation, Moscow, 119991
K. A. Babeshkin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: petros@igic.ras.ru
Russian Federation, Moscow, 119991
E. V. Belova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Moscow State University
Email: petros@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119991
A. V. Gavrikov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: petros@igic.ras.ru
Russian Federation, Moscow, 119991
N. N. Efimov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: petros@igic.ras.ru
Russian Federation, Moscow, 119991
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