电邮这篇文章 Dysprosium Thiocyanate Complexes with s-Triazine
- 作者: Petrosyants S.P.1, Ilyukhin A.B.1, Babeshkin K.A.1, Belova E.V.1,2, Gavrikov A.V.1, Efimov N.N.1
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隶属关系:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Moscow State University
- 期: 卷 45, 编号 8 (2019)
- 页面: 592-599
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214817
- DOI: https://doi.org/10.1134/S1070328419080062
- ID: 214817
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详细
The reaction of Dy(NCS)3 · 6H2O with 2,4,6-tris(2-pyridyl)-s-triazine (Tptz) in МеОН, MeCN, and H2O affords mononuclear neutral and ionic thiocyanate complexes with tridentate ligand Tptz: [Dy(H2O)(MeOH)(Tptz)(NCS)3] · Tptz (I), [Dy(Tptz)2(NCS)3] · MeCN (II), and [Dy(H2O)3-(Tptz)(NCS)2] · NCS · Tptz · 1.5H2O · 1.25MeOH (III). Structural features of the synthesized compounds are determined using powder XRD, IR spectroscopy, and thermoanalytical methods (thermogravimetry and differential scanning calorimetry). Compounds II and III exhibit the properties of single-molecule magnets.
作者简介
S. Petrosyants
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: petros@igic.ras.ru
俄罗斯联邦, Moscow, 119991
A. Ilyukhin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: petros@igic.ras.ru
俄罗斯联邦, Moscow, 119991
K. Babeshkin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: petros@igic.ras.ru
俄罗斯联邦, Moscow, 119991
E. Belova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Moscow State University
Email: petros@igic.ras.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991
A. Gavrikov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: petros@igic.ras.ru
俄罗斯联邦, Moscow, 119991
N. Efimov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: petros@igic.ras.ru
俄罗斯联邦, Moscow, 119991
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