Email this article The Reaction of Re3Br9 with P(CH2OH)3: Diversity of Modes of Coordination of Hydroxymethylphosphine to Clusters
- Authors: Anyushin A.V.1, Abramov P.A.1,2, Sokolov M.N.1,2,3
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- Kazan (Volga Region) Federal University
- Issue: Vol 45, No 8 (2019)
- Pages: 548-554
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214795
- DOI: https://doi.org/10.1134/S1070328419080013
- ID: 214795
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Abstract
The reaction of Re3Br9 with P(CH2OH)3 (THP) in methanol under inert atmosphere gives a new cluster complex, [Re3(µ2‑Br)3Br3(µ3-P,O,O-P(CH2OH)(CH2O)2)2H] ∙ 0.8H2O · 1.6MeOH (I). With access of air, the reaction produces a different product, [{Re3(µ2-Br)3Br2(OCH2)2PCH2-OP(CH2OH)2}2-{(P(CH2OH)(CH2O)2)}2] (II), in which two triangular clusters are linked by deprotonated THP molecules as bridging ligands. In addition, each cluster is coordinated in a tetradentate fashion by the phosphine-phosphinite ligand, resulting from the oxidative condensation of two THP molecules (CIF files CCDC 1829565 (I) and 1829566 (II)).
About the authors
A. V. Anyushin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: caesar@niic.nsc.ru
Russian Federation, Novosibirsk
P. A. Abramov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: caesar@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk
M. N. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University; Kazan (Volga Region) Federal University
Author for correspondence.
Email: caesar@niic.nsc.ru
Russian Federation, Novosibirsk; Novosibirsk; Kazan
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