Metallocenyl-containing and Unsaturated Fulleropyrrolidine Derivatives: Synthesis and Hydrogenation

N. V. Abramova; V. A. Shmakova; A. P. Pleshkova; V. I. Sokolov

doi:10.1134/S1070328419020015

Metallocenyl-containing and Unsaturated Fulleropyrrolidine Derivatives: Synthesis and Hydrogenation

Authors: Abramova N.V.¹, Shmakova V.A.¹, Pleshkova A.P.¹, Sokolov V.I.¹
Affiliations:
1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Issue: Vol 45, No 2 (2019)
Pages: 124-127
Section: Article
URL: https://journals.rcsi.science/1070-3284/article/view/214630
DOI: https://doi.org/10.1134/S1070328419020015
ID: 214630

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Abstract

The possibility of Pd/C-catalyzed hydrogenation of ferrocenyl, cymantrenyl, and ruthenocenyl derivatives of N-methyl-2-(3-chlorovinyl)fulleropyrrolidine and N-methyl-2-(2-styryl)fulleropyrrolidine with hydrogen was elucidated. A new compound, N-methyl-2-(3-chlorovinyl-3-ruthenocenyl)fulleropyrrolidine, was synthesized.