Отправить статью по E-mail New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re6(μ3-Q)8}(CN)6]4– (Q = S, Se, Te)
- Авторы: Pronin A.S.1,2, Yarovoy S.S.1, Smolentsev A.I.1,2, Mironov Y.V.1,2
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Учреждения:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- Выпуск: Том 45, № 2 (2019)
- Страницы: 119-123
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214625
- DOI: https://doi.org/10.1134/S1070328419020052
- ID: 214625
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Аннотация
A new method is proposed for the synthesis of the octahedral rhenium chalcocyanide cluster complexes [{Re6(μ3-Q)8}(CN)6]4– (Q = S, Se, Te) using rhenium(IV) oxide as the starting compound. Among the synthesized compounds, the anhydrous cluster salt K4[{Re6Se8}(CN)6] is characterized by X-ray diffraction analysis for the first time. The crystals are orthorhombic, space group Pbcn; a = 13.1386(13), b = 11.4941(8), c = 17.2990(16) Å, Z = 4, V = 2612.4(4) Å3 (CIF file IСSD no. 434320). The crystal structure of K4[{Re6Se8}(CN)6] represents a framework type packing based on the K+ cations coordinated by the cyanide groups of the cluster anions [{Re6Se8}(CN)6]4–.
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Об авторах
A. Pronin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: yuri@niic.nsc.ru
Россия, Novosibirsk, 630090 ; Novosibirsk, 630090
S. Yarovoy
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
Email: yuri@niic.nsc.ru
Россия, Novosibirsk, 630090
A. Smolentsev
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: yuri@niic.nsc.ru
Россия, Novosibirsk, 630090 ; Novosibirsk, 630090
Yu. Mironov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Автор, ответственный за переписку.
Email: yuri@niic.nsc.ru
Россия, Novosibirsk, 630090 ; Novosibirsk, 630090
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