Email this article Synthesis and Optoelectronic Properties of a Pt(II) Complex with 2-Pyridin-2-Yl-1,3-Thiazole-4-Carboxylic Acid
- Authors: Zhang X.P.1,2, Zhang D.S.1,2, Sun W.1,2, Shi Z.F.1,2
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Affiliations:
- College of Chemistry and Chemical Engineering
- Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province
- Issue: Vol 44, No 1 (2018)
- Pages: 15-20
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214322
- DOI: https://doi.org/10.1134/S1070328418010098
- ID: 214322
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Abstract
A carboxyl functionalized Pt(II) complex PtC9H6N2O2SCl2 (I) has been synthesized by the coordination reaction of K2PtCl4 with 2-pyridin-2-yl-1,3-thiazole-4-carboxylic acid. The absorption property and photosensitizing performance of I has been studied. Through assembling the dye-sensitized solar cells (DSSCs) based on complex I, a weak solar-energy-to-electricity conversion is presented. Additionally, when complex I was solved in DMF solution, a novel complex PtC9H7N2O3SCl (II) could be obtained. The structure of II has been confirmed by the single-crystal X-ray diffraction (CIF file CCDC no. 1538911).
About the authors
X. P. Zhang
College of Chemistry and Chemical Engineering; Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province
Email: zaifengshi_hnnu@sina.com
China, Haikou, 571158; Haikou, 571158
D. S. Zhang
College of Chemistry and Chemical Engineering; Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province
Email: zaifengshi_hnnu@sina.com
China, Haikou, 571158; Haikou, 571158
W. Sun
College of Chemistry and Chemical Engineering; Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province
Email: zaifengshi_hnnu@sina.com
China, Haikou, 571158; Haikou, 571158
Z. F. Shi
College of Chemistry and Chemical Engineering; Key Laboratory of Water Pollution Treatment & Resource Reuse of Hainan Province
Author for correspondence.
Email: zaifengshi_hnnu@sina.com
China, Haikou, 571158; Haikou, 571158
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