Nanostructured Catalysts of Methanol Electrooxidation Based on Platinum–Ruthenium–Palladium and Platinum–Ruthenium–Iridium Alloys Derived from Coordination Compounds


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Activities of the synthesized trimetallic catalysts PtRuPd/C and PtRuIr/C supported on highly dispersed carbon soot from solutions of coordination compounds of the corresponding metals are studied in the electrooxidation of methanol. According to the data of voltammetry, the Pt0.43Ru0.47Pd0.1/C and Pt0.44Ru0.46Ir0.1/C catalysts are not inferior to the commercial catalyst Pt0.5Ru0.5/C in specific characteristics, which is consistent with the data of structural studies and the electrochemical and power characteristics of the membrane electrode unit tested in the composition of a single methanol/air fuel cell.

作者简介

V. Vysotskii

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: aapasgugl@gmail.com
俄罗斯联邦, Moscow, 119991

N. Maiorova

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: aapasgugl@gmail.com
俄罗斯联邦, Moscow, 119991

V. Grinberg

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: aapasgugl@gmail.com
俄罗斯联邦, Moscow, 119991

A. Pasynskii

Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: aapasgugl@gmail.com
俄罗斯联邦, Moscow, 119991

A. Modestov

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: aapasgugl@gmail.com
俄罗斯联邦, Moscow, 119991

A. Shiryaev

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences

Email: aapasgugl@gmail.com
俄罗斯联邦, Moscow, 119991

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