Thermodynamic Characteristics of the Cadmium Pivalate Phenanthroline Complex Cd 2 Piv 4 Phen 2

D. B. Kayumova; I. P. Malkerova; M. A. Shmelev; A. A. Sidorov; I. L. Eremenko; A. S. Alikhanyan

doi:10.1134/S1070328418120035

Thermodynamic Characteristics of the Cadmium Pivalate Phenanthroline Complex Cd₂Piv₄Phen₂

Authors: Kayumova D.B.¹, Malkerova I.P.¹, Shmelev M.A.¹, Sidorov A.A.¹, Eremenko I.L.¹, Alikhanyan A.S.¹
Affiliations:
1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Issue: Vol 44, No 12 (2018)
Pages: 728-732
Section: Article
URL: https://journals.rcsi.science/1070-3284/article/view/214211
DOI: https://doi.org/10.1134/S1070328418120035
ID: 214211

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Abstract

Evaporation of the cadmium pivalate phenanthroline complex Cd₂Piv₄Phen₂ was studied by the Knudsen effusion method with mass spectral analysis of gas phase composition. The evaporation is congruent, and the gas phase consists of CdPiv₂Phen molecules. The standard enthalpy of sublimation of these molecules was found. The energy of dissociation of CdPiv₂Phen molecules to cadmium pivalate and phenanthroline was determined on the basis of experimental data on ionization.