Email this article p-Cymene Ruthenium Halide Complexes with a Heterocyclic Carbene
- Authors: Shapovalov S.S.1, Tikhonova O.G.1, Pasynskii A.A.1, Skabitskii I.V.1, Sakharov S.G.1
-
Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Issue: Vol 44, No 12 (2018)
- Pages: 709-715
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214199
- DOI: https://doi.org/10.1134/S1070328418120096
- ID: 214199
Cite item
Open Access
Access granted
Subscription Access
Abstract
The reaction of (p-cymene)Ru(Me2Im)Cl2 with excess Me2ImCO2 in acetonitrile in the presence of NH4PF6 afforded the amino complex [(p-cymene)Ru(Me2Im)(NH3)Cl]PF6. The reaction of (p‑cymene)Ru(Me2Im)Cl2 with excess anhydrous SnCl2 gave the complex (p-cy-mene)-Ru(Me2Im)Cl(SnCl3), whereas treatment of dimeric iodide complex [(p-cymene)RuI2]2 with Me2ImCO2 in acetonitrile gave the ionic compound [Me2ImH][(p-cymene)RuI3]. CIF files: CCDC nos. 1841649 (I), 1841650 (II), 1841648 (III).
About the authors
S. S. Shapovalov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: schss@yandex.ru
Russian Federation, Moscow, 119991
O. G. Tikhonova
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: schss@yandex.ru
Russian Federation, Moscow, 119991
A. A. Pasynskii
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: schss@yandex.ru
Russian Federation, Moscow, 119991
I. V. Skabitskii
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: schss@yandex.ru
Russian Federation, Moscow, 119991
S. G. Sakharov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: schss@yandex.ru
Russian Federation, Moscow, 119991
Supplementary files
