Email this article Mononuclear Molybdenum Oxohalide Complexes (Bu4N)[MoOCl4(H2O)] and (Bu4N)[MoOBr4(H2O)]: Synthesis and Crystal Structures
- Authors: Adonin S.A.1,2, Udalova L.I.2, Abramov P.A.1,2, Sokolov M.N.1,3, Fedin V.P.1,2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences
- Novosibirsk State University
- Kazan (Volga Region) Federal University
- Issue: Vol 44, No 11 (2018)
- Pages: 673-677
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214163
- DOI: https://doi.org/10.1134/S1070328418110015
- ID: 214163
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Abstract
The oxidation of K3[MoCl6] with air oxygen in aqueous solutions of HX (X = Cl, Br) in the presence of n-tetrabutylammonium salts affords mononuclear heteroligand complexes (Bu4N)[MoOCl4(H2O)] (I) and (Bu4N)[MoOBr4(H2O)] (II). The complexes are characterized by X-ray diffraction analysis (СIF files CCDC nos. 1812657 (I) and 1812658 (II).
About the authors
S. A. Adonin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Author for correspondence.
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
L. I. Udalova
Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090
P. A. Abramov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
M. N. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Kazan (Volga Region) Federal University
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Kazan
V. P. Fedin
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
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