Adsorption of the Monohydrogen Nitrilotris(methylenephosphonato)hydroxylaminatonitrosyl Molybdate Complex on the Steel Surface and Its Thermochemical Behavior in the Isolated State and in Adsorbed Layers
- Authors: Chausov F.F.1,2, Lomova N.V.1, Isupov N.Y.1, Shabanova I.N.1, Petrov V.G.3, Zhirov D.K.3
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Affiliations:
- Physical and Technical Institute, Ural Branch, Russian Academy of Sciences
- Udmurt State University
- Institute of Mechanics, Ural Branch, Russian Academy of Sciences
- Issue: Vol 44, No 10 (2018)
- Pages: 642-646
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214139
- DOI: https://doi.org/10.1134/S1070328418100019
- ID: 214139
Cite item
Abstract
The adsorption and thermochemical behavior of the heteroleptic molybdenum(III) complex with nitrilotris(methylenephosphonic acid), hydroxylamine, and nitrogen(II) oxide are studied by X-ray photoelectron spectroscopy in situ. The adsorption of the complex on the steel surface is accompanied by the partial oxidation of molybdenum. Upon the thermal action, the free complex is reduced to Mo(II) and that in the adsorbed layer is reduced to metallic molybdenum. This makes it possible to use the complex described as a precursor for surface alloying of steel units.
About the authors
F. F. Chausov
Physical and Technical Institute, Ural Branch, Russian Academy of Sciences; Udmurt State University
Author for correspondence.
Email: chaus@yandex.ru
Russian Federation, Izhevsk, 426000; Izhevsk, 426034
N. V. Lomova
Physical and Technical Institute, Ural Branch, Russian Academy of Sciences
Email: chaus@yandex.ru
Russian Federation, Izhevsk, 426000
N. Yu. Isupov
Physical and Technical Institute, Ural Branch, Russian Academy of Sciences
Email: chaus@yandex.ru
Russian Federation, Izhevsk, 426000
I. N. Shabanova
Physical and Technical Institute, Ural Branch, Russian Academy of Sciences
Email: chaus@yandex.ru
Russian Federation, Izhevsk, 426000
V. G. Petrov
Institute of Mechanics, Ural Branch, Russian Academy of Sciences
Email: chaus@yandex.ru
Russian Federation, Izhevsk, 426067
D. K. Zhirov
Institute of Mechanics, Ural Branch, Russian Academy of Sciences
Email: chaus@yandex.ru
Russian Federation, Izhevsk, 426067