Email this article Unusual Bridging Coordination Modes of THF and Piv Anions in the Hexanuclear Nickel(II) Carboxylate Complex
- Authors: Gogoleva N.V.1, Aleksandrov G.G.1, Kiskin M.A.1, Sidorov A.A.1, Eremenko I.L.1,2
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Affiliations:
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 44, No 10 (2018)
- Pages: 585-588
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/214102
- DOI: https://doi.org/10.1134/S1070328418100044
- ID: 214102
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Abstract
The recrystallization of complex [Ni9(OH)6(Piv)12(HPiv)4] (Piv– is anion of trimethylacetic acid) from a THF–MeCN (6 : 1) mixture gives a new hexanuclear compound of nickel(II): [Ni6(µ3-OH)2(Piv)10(THF)4]. Its structure (CIF file CCDC no. 1579976) exhibits rare examples of coordination of the µ2-THF and µ4-Piv ligands.
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About the authors
N. V. Gogoleva
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991
G. G. Aleksandrov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991
M. A. Kiskin
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991
A. A. Sidorov
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991
I. L. Eremenko
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences; Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mkiskin@igic.ras.ru
Russian Federation, Moscow, 119991; Moscow, 119991
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