Email this article Zn-containing double complex salts formed by Keggin type polyoxotungstates: Synthesis and crystal structure
- Authors: Udalova L.I.1, Adonin S.A.1,2, Abramov P.A.1,2, Korolkov I.V.1,2, Sokolov M.N.2,3
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Affiliations:
- Novosibirsk State University
- Nikolaev Institute of Inorganic Chemistry, Siberian Branch
- Butlerov Institute of Chemistry
- Issue: Vol 43, No 6 (2017)
- Pages: 368-372
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213927
- DOI: https://doi.org/10.1134/S1070328417050086
- ID: 213927
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Abstract
Novel double complex salts, [Zn(DMF)6]2[SiW12O40] · 2H2O (I) and [Zn(H2O)2(DMF)4][Zn(DMF)6]2[PW12O40]2 · 6DMF (II) (DMF = N,N-dimethylformamide), were prepared by the reaction of Zn2+ and heteropoly acids Hx[EW12O40] · xH2O (E = P, X = 3, E = Si, X = 4) in DMF. Compounds I and II were studied by X-ray diffraction (СIF files CCDC nos. 1497570 (I) and 1497571 (II)) and IR spectroscopy.
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About the authors
L. I. Udalova
Novosibirsk State University
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090
S. A. Adonin
Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Author for correspondence.
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
P. A. Abramov
Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
I. V. Korolkov
Novosibirsk State University; Nikolaev Institute of Inorganic Chemistry, Siberian Branch
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Novosibirsk, 630090
M. N. Sokolov
Nikolaev Institute of Inorganic Chemistry, Siberian Branch; Butlerov Institute of Chemistry
Email: adonin@niic.nsc.ru
Russian Federation, Novosibirsk, 630090; Kazan, 420008
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