Email this article Nanostructured catalysts for direct electrooxidation of dimethyl ether based on Bi- and trimetallic Pt–Ru and Pt–Ru–Pd alloys prepared from coordination compounds
- Authors: Grinberg V.A.1, Maiorova N.A.1, Pasynskii A.A.2, Emets V.V.1, Shiryaev A.A.1, Vysotskii V.V.1, Gerasimov V.K.1, Matveev V.V.1, Nizhnikovskii E.A.1, Andreev V.N.1
-
Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 43, No 4 (2017)
- Pages: 206-212
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213831
- DOI: https://doi.org/10.1134/S1070328417040017
- ID: 213831
Cite item
Open Access
Access granted
Subscription Access
Abstract
Bi- and trimetallic platinum–ruthenium and platinum–ruthenium–palladium catalysts with specified atomic ratios Pt: Ru = 1: 1 and Pt: Ru: Pd = 1: 1: 0.1, respectively, were synthesized from the coordination compounds of the metals deposited on highly dispersed carbon black. The catalysts were characterized by powder X-ray diffraction, electron dispersive analysis, and transmission electron microscopy. According to voltammetry data, the highest activity in the dimethyl ether (DME) electrooxidation is exhibited by the catalyst Pt0.43Ru0.47Pd0.1/C; hence, it may be considered as a promising anode material for direct DME fuel cells.
About the authors
V. A. Grinberg
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: vgrinberg@phyche.ac.ru
Russian Federation, Moscow, 117071
N. A. Maiorova
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: aapas@gmail.com
Russian Federation, Moscow, 117071
A. A. Pasynskii
Kurnakov Institute of General and Inorganic Chemistry
Author for correspondence.
Email: aapas@gmail.com
Russian Federation, Moscow, 117907
V. V. Emets
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: aapas@gmail.com
Russian Federation, Moscow, 117071
A. A. Shiryaev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: aapas@gmail.com
Russian Federation, Moscow, 117071
V. V. Vysotskii
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: aapas@gmail.com
Russian Federation, Moscow, 117071
V. K. Gerasimov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: aapas@gmail.com
Russian Federation, Moscow, 117071
V. V. Matveev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: aapas@gmail.com
Russian Federation, Moscow, 117071
E. A. Nizhnikovskii
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: aapas@gmail.com
Russian Federation, Moscow, 117071
V. N. Andreev
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: aapas@gmail.com
Russian Federation, Moscow, 117071
Supplementary files
