Email this article Syntheses, Crystal Structures, and Properties of Two d10 Metal Complexes Based on Ferrocenyl Ligands Bearing Pyrazolyl Pyridine Substituents
- Authors: Liu W.1, Li X.1, Chen H.H.1, Wu B.L.2, Zhang H.Y.2
-
Affiliations:
- College of Materials and Chemical Engineering
- College of Chemistry and Molecular Engineering
- Issue: Vol 44, No 1 (2018)
- Pages: 72-81
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213708
- DOI: https://doi.org/10.1134/S1070328417120053
- ID: 213708
Cite item
Open Access
Access granted
Subscription Access
Abstract
Two new complexes, namely, [Cd2(L1)2(NCS)4(DMF)2] · 4H2O (I) and {[Zn3(L2)4(SO4)3(H2O)8] · 3DMF · 6H2O}n (II) have been synthesized through self-assembly of Cd(II) or Zn(II) salts with ferrocenyl ligands bearing pyrazolyl pyridine substituents. The two compounds were characterized by IR spectra, element analysis, X-ray powder diffraction, single-crystal X-ray diffraction (СIF files CCDC nos. 949526 (I), 949527 (II)), and thermogravimetric analysis. Complex I crystallizes in the monocline space group P21/c and exhibits a discrete dinuclear structure. The adjacent dinuclear molecules are packed into a 1D linear chain through the hydrogen-bond interactions. Complex II is a neutral one-dimensional infinite zigzag coordination chain. The 3D packing diagram of II contains two types of voids and the solvated DMF and water molecules filled them and stabilized by the hydrogen bonds. In addition, the redox properties of both complexes I and II have also been investigated.
About the authors
W. Liu
College of Materials and Chemical Engineering
Email: lixia@hncj.edu.cn
China, Pingdingshan, Henan, 467044
X. Li
College of Materials and Chemical Engineering
Author for correspondence.
Email: lixia@hncj.edu.cn
China, Pingdingshan, Henan, 467044
H. H. Chen
College of Materials and Chemical Engineering
Email: lixia@hncj.edu.cn
China, Pingdingshan, Henan, 467044
B. L. Wu
College of Chemistry and Molecular Engineering
Email: lixia@hncj.edu.cn
China, Zhengzhou, Henan, 450052
H. Y. Zhang
College of Chemistry and Molecular Engineering
Email: lixia@hncj.edu.cn
China, Zhengzhou, Henan, 450052
Supplementary files
