Email this article Lanthanum complex with mono- and dideprotonated diketoimine
- Authors: Petrov P.A.1,2, El’tsov I.V.2
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Affiliations:
- Nikolaev Institute of Inorganic Chemistry
- Novosibirsk State University
- Issue: Vol 43, No 9 (2017)
- Pages: 600-603
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213519
- DOI: https://doi.org/10.1134/S1070328417090068
- ID: 213519
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Abstract
The reaction of LaCl3 with ß-diketoimine potassium salt KDipp,MeNacnac (KL) affords the molecular complex [LaLL'] with singly and doubly deprotonated diketoimine. The complex is characterized by single- crystal X-ray diffraction analysis (CIF file CCDC 1528658). The structure of [LaLL'] in solution is studied by 1D and 2D 1H and 13C NMR spectroscopy.
About the authors
P. A. Petrov
Nikolaev Institute of Inorganic Chemistry; Novosibirsk State University
Author for correspondence.
Email: panah@niic.nsc.ru
Russian Federation, pr. akademika Lavrent’eva 3, Novosibirsk, 630090; ul. Pirogova 2, Novosibirsk, 630090
I. V. El’tsov
Novosibirsk State University
Email: panah@niic.nsc.ru
Russian Federation, ul. Pirogova 2, Novosibirsk, 630090
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