Email this article Copper(II) complexes based on 2-thenoyltrifluoroacetone aroyl hydrazones: Synthesis, spectroscopy, and X-ray diffraction analysis
- Authors: Avezov K.G.1, Umarov B.B.1, Tursunov M.A.1, Minin V.V.2, Parpiev N.A.1
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Affiliations:
- Bukhara State University
- Kurnakov Institute of General and Inorganic Chemistry
- Issue: Vol 42, No 7 (2016)
- Pages: 470-475
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213451
- DOI: https://doi.org/10.1134/S1070328416070010
- ID: 213451
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Abstract
Copper(II) complexes CuL • NH3 are synthesized by the interaction of ethanol solutions of parasubstituted 2-thenoyltrifluoroacetylmethane aroyl hydrazones (H2L1–H2L4) and an aqueous-ammonia solution of copper(II) acetate in an equimolar ratio. The copper(II) complexes are studied by elemental analysis, IR spectroscopy, and EPR spectroscopy. Single crystals of CuL3 • NH3 are grown from 1-(2-thenoyl)- 3,3,3-trifluoroacetone para-methylbenzoyl hydrazone and studied using X-ray diffraction analysis (CIF file CCDC 1045841).
About the authors
K. G. Avezov
Bukhara State University
Author for correspondence.
Email: avezovkg@mail.ru
Uzbekistan, Bukhara
B. B. Umarov
Bukhara State University
Email: avezovkg@mail.ru
Uzbekistan, Bukhara
M. A. Tursunov
Bukhara State University
Email: avezovkg@mail.ru
Uzbekistan, Bukhara
V. V. Minin
Kurnakov Institute of General and Inorganic Chemistry
Email: avezovkg@mail.ru
Russian Federation, Leninskii pr. 31, Moscow, 119991
N. A. Parpiev
Bukhara State University
Email: avezovkg@mail.ru
Uzbekistan, Bukhara
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