Email this article Two novel 2D cadmium compounds with noncentrosymmetric or symmetric network dependent on different pH values
- Authors: Xue C.C.1, Li M.X.1, Shao M.2, Wang Z.X.1
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Affiliations:
- Department of Chemistry, Innovative Drug Research Center
- Instrumental Analysis and Research Center
- Issue: Vol 42, No 7 (2016)
- Pages: 442-448
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213437
- DOI: https://doi.org/10.1134/S1070328416070058
- ID: 213437
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Abstract
Hydrothermal reaction of cadmium chloride and 2-carboxyethyl(phenyl)phosphinic acid (H2L) under pH 2.69 or 5.00 afforded two novel Cd(II) compounds with the formula of [Cd(HL)2]n (I) and [Cd3(L)2(OH)2]n (II), respectively. Both compounds were well characterized by elemental analysis, IR spectroscopy, power X-ray diffraction, fluorescence and single-crystal X-ray diffraction (CIF files CCDC nos. 1049809 (I), 1049810 (II)). Compound I crystallizes in a Pca21 space group and presents a two-dimensional (2D) layered noncentrosymmetric structure, in which slight difference of the two Cd–O(phosphinico) distances leads to the formation of the chiral phosphorus atom in HL– ligand. Compound II adopts a centrosymmetric P21/c space group and exhibits a 2D network. Both compounds show violet fluorescence, assigned as an intraligand emission.
About the authors
C. C. Xue
Department of Chemistry, Innovative Drug Research Center
Email: zxwang@shu.edu.cn
China, Shanghai, 200444
M. X. Li
Department of Chemistry, Innovative Drug Research Center
Email: zxwang@shu.edu.cn
China, Shanghai, 200444
M. Shao
Instrumental Analysis and Research Center
Email: zxwang@shu.edu.cn
China, Shanghai, 200444
Z. X. Wang
Department of Chemistry, Innovative Drug Research Center
Author for correspondence.
Email: zxwang@shu.edu.cn
China, Shanghai, 200444
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