Anion-assisted two group IIB metallic coordination architecture and luminescence performance
- Authors: Hu J.Y.1, Liao C.L.2, Zhang C.C.1, Chen S.F.1, Zhang J.S.1, Zhao J.A.1
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Affiliations:
- College of Chemical and Material Engineering
- College of Life Science and Engineering
- Issue: Vol 42, No 6 (2016)
- Pages: 378-384
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213421
- DOI: https://doi.org/10.1134/S1070328416060026
- ID: 213421
Cite item
Abstract
React of cadmium salts with 4,4'-bis((2-(pyridin-2-yl)-1H-benzo[d]imidazol-1-yl)methyl)biphenyl (Bpbib) yields two one-dimensional (1D) coordination architectures of two new complexes—{[Cd2(Bpbib)2(NO3)4] • CH3OH}n (I) and {[Cd(Bpbib)Cl2] • 2CH3OH}n (II). Complexes I and II were characterized by the elemental analyses, photoluminescence and emission spectra and single-crystal X-ray diffraction (CIF files CCDC nos. 1046021 (I), 1046022 (II)). Complex I is a helical array, whereas II features a zigzag pattern, depending upon the type of their associated anions. In addition to the primary organic linker, the counter anions also have a dominant influence on the overall structures, and even arouse the luminescence performance diversity.
About the authors
J. Y. Hu
College of Chemical and Material Engineering
Author for correspondence.
Email: hujiyong@hncj.edu.cn
China, Henan, 467036
C. L. Liao
College of Life Science and Engineering
Email: zjinan@zzu.edu.cn
China, Pingdingshan, Henan, 467036
C. C. Zhang
College of Chemical and Material Engineering
Email: zjinan@zzu.edu.cn
China, Henan, 467036
S. F. Chen
College of Chemical and Material Engineering
Email: zjinan@zzu.edu.cn
China, Henan, 467036
J. S. Zhang
College of Chemical and Material Engineering
Email: zjinan@zzu.edu.cn
China, Henan, 467036
J. A. Zhao
College of Chemical and Material Engineering
Author for correspondence.
Email: zjinan@zzu.edu.cn
China, Henan, 467036