Email this article Synthesis, characterization, and structure of a new ferromagnetically coupled tetranuclear nickel cubane complex
- Authors: Liu Y.1, Li W.1, Lu H.1, Sun J.1
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Affiliations:
- Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering
- Issue: Vol 42, No 3 (2016)
- Pages: 166-169
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213382
- DOI: https://doi.org/10.1134/S1070328416030052
- ID: 213382
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Abstract
A new nickel complexes [Ni(L)4(OCH3)4(CH3OH)4] (I) (HL = salicylaldehyde) was synthesized and structurally characterized by elemental analyses and single-crystal X-ray diffraction (CIF file CCDC no. 1410887). The complex crystallizes in monoclinic P21/c space group and consists of one crystallographically independent molecule which contains a distorted tetranuclear cubane core with alternating nickel and oxygen atoms of the four on the corners. The magnetic properties reveal the presence of ferromagnetic interactions between the nickel(II) centers in the cubic cluster with two different exchange pathways.
About the authors
Y. Liu
Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering
Email: sunjh@jsut.edu.cn
China, Changzhou, 213001
W. Li
Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering
Email: sunjh@jsut.edu.cn
China, Changzhou, 213001
H. Lu
Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering
Email: sunjh@jsut.edu.cn
China, Changzhou, 213001
J. Sun
Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering
Author for correspondence.
Email: sunjh@jsut.edu.cn
China, Changzhou, 213001
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