Email this article Two heterometallic complexes with a new macrocyclic oxamido complex ligand
- Authors: Li Y.H.1, Ma Z.G.1, Yuan B.1, Ding B.B.1, Li X.Z.1,2, Zhu L.N.1
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Affiliations:
- Department of Chemistry, School of Science
- State Key Laboratory of Crystal Material (Shandong University)
- Issue: Vol 42, No 8 (2016)
- Pages: 546-556
- Section: Article
- URL: https://journals.rcsi.science/1070-3284/article/view/213357
- DOI: https://doi.org/10.1134/S1070328416080030
- ID: 213357
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Abstract
A new macrocyclic oxamido-nickle(II) complex Na2NiL was synthesized. L denotes the doubly deprotonated forms of (13Z, 19Z)-16-methyl-6,7-dioxo-5,6,7,8-tetrahydrotriben-zo[b,f,l][1,4,8,11]tetraazacyclotetradecine- 13,20-dicarboxylate. Based on the complex ligand Ni(L2–), two heterometallic complexes [Ca2(NiL)2(H2O)8] · 10H2O (I) and [Co(NiL)2(H2O)2][Co(H2O)6] · 2.8H2O (II) were prepared. X-ray single crystal analyses (CCDC nos. 914618 (I), 914616 (II)) revealed that [Ca2(NiL)2(H2O)8] in I is a molecular box and the trinuclear complex anion [Co(NiL)2(H2O)2]2–in II is centrosymmetric. Thermogravimetric analyses showed that I exhibited moderately good stability and Co(II) catalyzed the thermal decomposition of II.
About the authors
Y. H. Li
Department of Chemistry, School of Science
Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 300072
Z. G. Ma
Department of Chemistry, School of Science
Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 300072
B. Yuan
Department of Chemistry, School of Science
Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 300072
B. B. Ding
Department of Chemistry, School of Science
Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 300072
X. Z. Li
Department of Chemistry, School of Science; State Key Laboratory of Crystal Material (Shandong University)
Author for correspondence.
Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 300072; Jinan, 250100
L. N. Zhu
Department of Chemistry, School of Science
Email: lixiaozeng321@tju.edu.cn
China, Tianjin, 300072
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