Trifluoroacetate complexes of 3 d  elements: Specific features of syntheses and structures

I. V. Morozov; E. V. Karpova; T. Yu. Glazunova; A. I. Boltalin; M. A. Zakharov; D. S. Tereshchenko; A. A. Fedorova; S. I. Troyanov

doi:10.1134/S107032841610002X

Trifluoroacetate complexes of 3d elements: Specific features of syntheses and structures

Authors: Morozov I.V.¹, Karpova E.V.¹, Glazunova T.Y.¹, Boltalin A.I.¹, Zakharov M.A.¹, Tereshchenko D.S.¹, Fedorova A.A.¹, Troyanov S.I.¹
Affiliations:
1. Moscow State University
Issue: Vol 42, No 10 (2016)
Pages: 647-661
Section: The Issue is Devoted to Carboxylate Complexes of Transition Metals
URL: https://journals.rcsi.science/1070-3284/article/view/213337
DOI: https://doi.org/10.1134/S107032841610002X
ID: 213337

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Abstract

Data on the syntheses and structures of trifluoroacetates of 3d elements mainly based on our results are reviewed. Specific features of the coordination chemistry of mono-, oligo-, and polynuclear trifluoroacetate complexes are successively considered. Special attention is given to oxo- and fluorotrifluoroacetates containing the trinuclear triangular fragment as a structural unit. Structural features of trifluoroacetates compared to other carboxylates are discussed.