Testing the reference Moon model in respect of the thermal regime and chemical composition of the mantle: Thermodynamics versus seismology

Abstract

The VPREMOON seismic reference Moon model (Garcia et al., 2011) has been tested with respect to the thermal regime and chemical composition of the mantle. Based on a self-consistent thermodynamic approach and petrological models of the lunar mantle covering a wide range of concentrations of CaO, Al₂O₃, and FeO, we convert the P- and S-wave velocity profiles to the temperature–depth profiles. The solution procedure relies on the method of the Gibbs free energy minimization and the equations of state for the mantle material which take into account the effects of phase transformations, anharmonicity, and anelasticity. We find that regardless of the chemical composition, the positive P- and S-wave velocity gradient in the lunar mantle leads to a negative temperature gradient, which has no physical basis. For adequate mantle temperatures, the P- and S-wave velocities should remain almost constant or slightly decrease with depth (especially V_S) as a result of the effects of the temperature, which grows faster than pressure. These findings underscore the importance of the relationship of the thermodynamics and physics of minerals with seismology.