Formation of coatings of mixed aluminum and manganese oxides on the AL25 alloy

Resumo

Features of plasma electrolytic oxidation of the AL25 cast complex-alloyed aluminum alloy are discussed. It has been shown that a variation in the nature and concentration ratio of the electrolyte compo- nents provides the formation of mixed-oxide coatings containing the materials of the basic matrix and the dopant. An increase in the coating thickness and the manganese oxide content in the coating is achieved by the homogenization of the treated surface owing to the simultaneous formation of oxides and the removal of alloying components of the alloy from the surface layers. Current density intervals that provide a uniform distribution of elements in the coating and a high efficiency of the Faraday and thermochemical reactions are determined. It is found that the stoichiometric oxygen index in MnO_x oxides is x = 1.71–1.87. Testing of the synthesized oxide systems in the model oxidation of carbon(II) oxide to CO₂ shows that the ignition and complete conversion temperatures are at the level of values characteristic of platinum catalysts.