Influence of Nickel Sulfate Additives to Electrolytes Subjected to Microarc Oxidation on the Structure, Composition, and Properties of Coatings Formed on Titanium


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The influence of nickel sulfate additives to acid and basic electrolytes for microarc oxidation on the structure, composition, and properties of coatings formed on VT1-0 titanium were studied to produce poorly soluble titanium anodes. We established the possibility of incorporating nickel (nickel oxide) into the composition of coatings. X-ray diffraction analysis showed that the coatings contained nickel oxide β-NiO with a cubic lattice, TiO2 in the form of rutile, and SiO2 in the form of high-temperature β-cristobalite. The maximum thickness and nickel content in the surface layer and the minimum values of both the anodic dissolution currents and the electrical strength were obtained for the coatings formed in silicate-alkali (3 g/L KOH + 4.5 g/L Na2SiO3) electrolyte with the addition of 1 g/L of nickel sulfate NiSO4.

Sobre autores

I. Kasatkina

Frumkin Institute of Physical Cheistry and Electrochemistry

Email: fg04@yandex.ru
Rússia, Moscow, 119071

B. Krit

Moscow Aviation Institute (National Research University) (MAI)

Email: fg04@yandex.ru
Rússia, Moscow, 109383

V. Lyudin

Moscow Aviation Institute (National Research University) (MAI)

Email: fg04@yandex.ru
Rússia, Moscow, 109383

I. Fedichkin

Moscow Aviation Institute (National Research University) (MAI)

Email: fg04@yandex.ru
Rússia, Moscow, 109383

A. Shcherbakov

Frumkin Institute of Physical Cheistry and Electrochemistry

Email: fg04@yandex.ru
Rússia, Moscow, 119071

A. Apelfeld

Moscow Aviation Institute (National Research University) (MAI)

Email: fg04@yandex.ru
Rússia, Moscow, 109383

N. Bogdashkina

Frumkin Institute of Physical Cheistry and Electrochemistry

Autor responsável pela correspondência
Email: fg04@yandex.ru
Rússia, Moscow, 119071

M. Gerasimov

Frumkin Institute of Physical Cheistry and Electrochemistry

Email: fg04@yandex.ru
Rússia, Moscow, 119071

R. Zalavutdinov

Frumkin Institute of Physical Cheistry and Electrochemistry

Email: fg04@yandex.ru
Rússia, Moscow, 119071

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