Influence of Nickel Sulfate Additives to Electrolytes Subjected to Microarc Oxidation on the Structure, Composition, and Properties of Coatings Formed on Titanium
- Authors: Kasatkina I.V.1, Krit B.L.2, Lyudin V.B.2, Fedichkin I.D.2, Shcherbakov A.I.1, Apelfeld A.V.2, Bogdashkina N.L.1, Gerasimov M.V.1, Zalavutdinov R.K.1
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Affiliations:
- Frumkin Institute of Physical Cheistry and Electrochemistry
- Moscow Aviation Institute (National Research University) (MAI)
- Issue: Vol 54, No 4 (2018)
- Pages: 331-337
- Section: Article
- URL: https://journals.rcsi.science/1068-3755/article/view/230773
- DOI: https://doi.org/10.3103/S106837551804004X
- ID: 230773
Cite item
Abstract
The influence of nickel sulfate additives to acid and basic electrolytes for microarc oxidation on the structure, composition, and properties of coatings formed on VT1-0 titanium were studied to produce poorly soluble titanium anodes. We established the possibility of incorporating nickel (nickel oxide) into the composition of coatings. X-ray diffraction analysis showed that the coatings contained nickel oxide β-NiO with a cubic lattice, TiO2 in the form of rutile, and SiO2 in the form of high-temperature β-cristobalite. The maximum thickness and nickel content in the surface layer and the minimum values of both the anodic dissolution currents and the electrical strength were obtained for the coatings formed in silicate-alkali (3 g/L KOH + 4.5 g/L Na2SiO3) electrolyte with the addition of 1 g/L of nickel sulfate NiSO4.
About the authors
I. V. Kasatkina
Frumkin Institute of Physical Cheistry and Electrochemistry
Email: fg04@yandex.ru
Russian Federation, Moscow, 119071
B. L. Krit
Moscow Aviation Institute (National Research University) (MAI)
Email: fg04@yandex.ru
Russian Federation, Moscow, 109383
V. B. Lyudin
Moscow Aviation Institute (National Research University) (MAI)
Email: fg04@yandex.ru
Russian Federation, Moscow, 109383
I. D. Fedichkin
Moscow Aviation Institute (National Research University) (MAI)
Email: fg04@yandex.ru
Russian Federation, Moscow, 109383
A. I. Shcherbakov
Frumkin Institute of Physical Cheistry and Electrochemistry
Email: fg04@yandex.ru
Russian Federation, Moscow, 119071
A. V. Apelfeld
Moscow Aviation Institute (National Research University) (MAI)
Email: fg04@yandex.ru
Russian Federation, Moscow, 109383
N. L. Bogdashkina
Frumkin Institute of Physical Cheistry and Electrochemistry
Author for correspondence.
Email: fg04@yandex.ru
Russian Federation, Moscow, 119071
M. V. Gerasimov
Frumkin Institute of Physical Cheistry and Electrochemistry
Email: fg04@yandex.ru
Russian Federation, Moscow, 119071
R. Kh. Zalavutdinov
Frumkin Institute of Physical Cheistry and Electrochemistry
Email: fg04@yandex.ru
Russian Federation, Moscow, 119071