Electrical Conductivity and Dielectric Permittivity of γ-Irradiated Nanocomposites Based on Ultrahigh-Molecular-Weight Polyethylene Filled with α-SiO2


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Abstract

UHMWPE/SiO2 composites were obtained from a homogeneous mixture of ultrahigh-molecular- weight polyethylene (UHMWPE) and silicon dioxide (α-SiO2) by hot pressing. The temperature dependence (20–170°C) of their conductivities σdс prior to and after γ irradiation (D = 200 kGy), the effect of absorbed dose on the σ value (dose dependence), the behavior of the function logσdc = f(T) under heating–cooling conditions, and the frequency dependences (25–106 Hz) of the real (ε') and imaginary (ε'') parts of the complex dielectric constant were studied. The logσdc = f(T) dependence was shown to have in both cases a complex pattern: “breaks” due to phase transitions were observed. With an increase in the concentration of α-SiO2, the ε' and ε'' (tanδ) values in the matrix increased and the frequency dependences of these values corresponded to an exponential rule.

About the authors

R. S. Ismaiilova

Institute of Radiation Problems

Author for correspondence.
Email: rafiqa55@rambler.ru
Azerbaijan, Baku, Az-1143

A. M. Magerramov

Institute of Radiation Problems

Email: rafiqa55@rambler.ru
Azerbaijan, Baku, Az-1143

M. M. Kuliev

Institute of Radiation Problems

Email: rafiqa55@rambler.ru
Azerbaijan, Baku, Az-1143

G. A. Akhundova

Azerbaijan State Marine Academy

Email: rafiqa55@rambler.ru
Azerbaijan, Baku, Az-1000

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