Plasma electrolytic treatment of VT22 titanium alloy in electrolytes with carbon-containing compounds

Resumo

The study investigates the influence of electrolyte compositions containing acetone, glycerol, sucrose, ethylene glycol and ammonium chloride on the properties of VT22 titanium alloy in the process of the anode plasma electrolytic treatment (PET). An X-ray diffractometer and a scanning electron microscopy (SEM) were used to characterize the phase composition and morphology of the modified surface. Tribological properties of the treated titanium alloy were evaluated using a pin-on-disc tribometer under lubricated testing conditions. The effect of electrolyte compositions on the corrosion resistance of the PET samples was examined by means of potentiodynamic polarization in a solution of Na₂SO₄. It was assumed that the PET provides the saturation of titanium alloy with oxygen and carbon and formation TiO₂ with a rutile structure and carbon solid solution in titanium. The anode PET in an electrolyte with glycerol results in an increase in microhardness to 540 HV and a decrease in the corrosion current density by 2.4 times. The friction coefficient of the treated samples in anelectrolyte with sucrose can be reduced 7.5 times. The anode PET in all electrolytes enables todiminish the wear rate of the titanium alloy samples by 3 orders of magnitude and the surface roughness, too, due to the anode dissolution of titanium.