A compact form for the analytic description of temperature dependence of saturation vapor pressure over plane surfaces of water and ice

Аннотация

A possibility is studied of extending the range of action of the simple three-parameter formula (ITS-90 scale) proposed in the previous work of the author [2] for the dependence of saturation vapor pressure E on temperature T within the range of 250 to 490 K. The results demonstrated that the dependence ln[E(T)/E(T_bas)] = (T - T_bas)[A - B(T - T_bas) + C(T - T_bas)²]/T with four sets of coefficients A, B, and C obtained using one base temperature Tbas equal to the temperature of triple point of water T_t = 273.16 K and two additional base values T_bas2 = 473.16 K and T_bas3 = 623.16 K makes it possible to approximate rather accurately the initial experimental and computed data in the temperature range from the point of homogeneous freezing of 235 K to the critical temperature of 647 K for liquid water and from 193 K to T_t for ice. A procedure used for obtaining the inverse function T(E) by solving the third-degree algebraic equation is validated. A hypothesis is proposed for the physical substantiation of additional base points in the form of “a noticeable appearance of dimers at the point T_bas2 and their 100% concentration at the temperature T_bas3.”