Vibrationally Excited Ozone Relaxation by CO


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Time profiles of ozone concentration after pulsed UV laser photolysis in the O2- O3-Ar-CO mixture, measured using time-resolved absorption spectroscopy, are presented. The experimental results show the dominance of the stabilization channel over the reactive one for the interaction between the vibrationally excited ozone molecule O3(υ) and carbon monoxide CO. The rate constant of the process O3(υ)+CO→O3 + CO, obtained by processing experimental data by the kinetic modeling method is (1.5 ± 0.2) · 10−13 cm3/s.

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A. Torbin

Samara Branch of the Lebedev Physical Institute; Samara National Research University

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Email: torbinalex@gmail.com
俄罗斯联邦, ul. Novo-Sadovaya 221, Samara, 443011; Moskovskoye shosse 34, Samara, 443086

A. Pershin

Samara Branch of the Lebedev Physical Institute; Samara National Research University

Email: torbinalex@gmail.com
俄罗斯联邦, ul. Novo-Sadovaya 221, Samara, 443011; Moskovskoye shosse 34, Samara, 443086

A. Mebel

Samara National Research University; Florida International University.

Email: torbinalex@gmail.com
俄罗斯联邦, Moskovskoye shosse 34, Samara, 443086; 11200 SW 8th St, Miami, FL, 33199

V. Azyazov

Samara Branch of the Lebedev Physical Institute; Samara National Research University

Email: torbinalex@gmail.com
俄罗斯联邦, ul. Novo-Sadovaya 221, Samara, 443011; Moskovskoye shosse 34, Samara, 443086

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