Email this article Kinetics of C10H7Br Pyrolysis
- Authors: Zagidullin M.V.1,2, Kaiser R.I.3, Ahmed M.4, Porfiriev D.P.1, Medvedkov I.A.1, Mebel A.M.1,5, Azyazov V.N.1,2
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Affiliations:
- Samara National Research University
- Lebedev Physical Institute, Samara Branch
- University of Hawaii at Manoa
- Lawrence Berkeley National Laboratory
- Florida International University
- Issue: Vol 45, No 10 (2018)
- Pages: 314-317
- Section: Article
- URL: https://journals.rcsi.science/1068-3356/article/view/228786
- DOI: https://doi.org/10.3103/S106833561810007X
- ID: 228786
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Abstract
The temperature and pressure-dependent rate constants for the process C10H7Br ↔ C10H7+Br were evaluated using the variable reaction coordinate transition state theory VRC-TST. The calculated rate constants and computational fluid dynamics (CFD) calculations were employed to estimate the pyrolysis efficiency of 2-bromonaphthalene in the resistively-heated SiC high-temperature “chemical reactor” at the temperature of about 1500 K. The observed 40% pyrolysis efficiency is reproduced by CFD calculations if the value of the calculated rate constant for the C10H7Br pyrolysis is increased by a factor of 2.
About the authors
M. V. Zagidullin
Samara National Research University; Lebedev Physical Institute, Samara Branch
Author for correspondence.
Email: zagidullin_marsel@rambler.ru
Russian Federation, Moskovskoe shosse 34, Samara, 443086; ul. Novo-Sadovaya 221, Samara, 443011
R. I. Kaiser
University of Hawaii at Manoa
Email: zagidullin_marsel@rambler.ru
United States, 2500 Campus Rd, Honolulu, Hawai’i, 96822
M. Ahmed
Lawrence Berkeley National Laboratory
Email: zagidullin_marsel@rambler.ru
United States, 1 Cyclotron Rd, Berkeley, California, 94720
D. P. Porfiriev
Samara National Research University
Email: zagidullin_marsel@rambler.ru
Russian Federation, Moskovskoe shosse 34, Samara, 443086
I. A. Medvedkov
Samara National Research University
Email: zagidullin_marsel@rambler.ru
Russian Federation, Moskovskoe shosse 34, Samara, 443086
A. M. Mebel
Samara National Research University; Florida International University
Email: zagidullin_marsel@rambler.ru
Russian Federation, Moskovskoe shosse 34, Samara, 443086; 11200 SW 8th St, Miami, Florida, 33199
V. N. Azyazov
Samara National Research University; Lebedev Physical Institute, Samara Branch
Email: zagidullin_marsel@rambler.ru
Russian Federation, Moskovskoe shosse 34, Samara, 443086; ul. Novo-Sadovaya 221, Samara, 443011
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