Equation of solvated ion oscillations in solution under an external periodic electric field

I. V. Shamanin; M. A. Kazaryan; S. N. Timchenko; A. D. Poberezhnikov

doi:10.3103/S1068335617100086

Equation of solvated ion oscillations in solution under an external periodic electric field

Authors: Shamanin I.V.¹, Kazaryan M.A.², Timchenko S.N.¹, Poberezhnikov A.D.¹
Affiliations:
1. National Research Tomsk Polytechnic University
2. Lebedev Physical Institute
Issue: Vol 44, No 10 (2017)
Pages: 308-312
Section: Article
URL: https://journals.rcsi.science/1068-3356/article/view/228479
DOI: https://doi.org/10.3103/S1068335617100086
ID: 228479

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Abstract

An equation describing ion oscillations with respect to solvent molecules is derived as a result of the consideration of the interaction of an external electric field with free and bound charges in the volume of a salt solution in a polar dielectric liquid. An analysis of the equation shows that the ion motion represents a drift toward one of the electrodes forming the field in the electroinsulated solution volume if amplitudes and durations of sinusoidal field half-periods are different.