Appearance of an artifact peak in the particle size distribution measured by DLS at low concentrations


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Abstract

The dynamic light scattering (DLS) method allows the determination of the particle size distribution of suspensions. At high dilutions, an artifact peak appears in the size distribution, which does not correspond to actual particles, but is caused by crossing the scattering volume boundaries by individual particles. The parameters of this peak are analyzed, the causes of its appearance and its effect on determined particle sizes are studied.

About the authors

M. N. Kirichenko

Lebedev Physical Institute

Author for correspondence.
Email: kirmari@sci.lebedev.ru
Russian Federation, Leninskii pr. 53, Moscow, 119991

A. T. Sanoeva

Lebedev Physical Institute

Email: kirmari@sci.lebedev.ru
Russian Federation, Leninskii pr. 53, Moscow, 119991

L. L. Chaikov

Lebedev Physical Institute; National Research Nuclear University “MEPhI”

Email: kirmari@sci.lebedev.ru
Russian Federation, Leninskii pr. 53, Moscow, 119991; Kashirskoe sh. 31, Moscow, 115409

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