Incomplete ozone recovery effect in the presence of active oxygen species


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Аннотация

The degree of ozone recovery after pulsed UV laser photolysis of O2-O3-Ar mixture is measured using time-resolved absorption spectroscopy. The effect of incomplete ozone recovery in the presence of molecular singlet oxygen O2(a1Δ) and atomic oxygen is detected. This effect is caused by the reaction between the vibrationally excited ozone molecule formed due to recombination and atomic oxygen. The branching factor for the chemical channel of reaction products is γr = 0.81 ± 0.13.

Авторлар туралы

A. Pershin

Branch of the Lebedev Physical Institute; Korolev Samara State Aerospace University

Email: azyazov@fian.smr.ru
Ресей, ul. Novo-Sadovaya 221, Samara, 443011; Moskovskoe sh. 34, Samara, 443086

A. Torbin

Branch of the Lebedev Physical Institute; Korolev Samara State Aerospace University

Email: azyazov@fian.smr.ru
Ресей, ul. Novo-Sadovaya 221, Samara, 443011; Moskovskoe sh. 34, Samara, 443086

M. Heaven

Korolev Samara State Aerospace University; Emory University

Email: azyazov@fian.smr.ru
Ресей, Moskovskoe sh. 34, Samara, 443086; 201 Dowman Drive, Atlanta, Georgia, 30322

V. Azyazov

Branch of the Lebedev Physical Institute; Korolev Samara State Aerospace University; Emory University

Хат алмасуға жауапты Автор.
Email: azyazov@fian.smr.ru
Ресей, ul. Novo-Sadovaya 221, Samara, 443011; Moskovskoe sh. 34, Samara, 443086; 201 Dowman Drive, Atlanta, Georgia, 30322

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