Conductive TiB2–AlN–BN-Based Composite SHS Ceramics

详细

The structure, phase composition, and electrical conductivity of TiB₂–AlN–BN-based ceramics fabricated by self-propagating high-temperature synthesis (SHS) are investigated. The temperature dependence of the specific electrical conductivity was measured in range T = 300–1300 K in vacuum of 2 × 10^–3 Pa according to the standard four-probe dc-current procedure. It is established that the TiN and BN contents in the synthesis products increase while those of TiB₂ and Al decrease with an increase in the TiB₂ content in the initial mixture from 60 to 80 wt % and a decrease in the Al concentration from 40 to 20 wt % because of the reaction of TiB₂ with nitrogen. A decrease in the Al concentration in the initial mixture leads to a decrease in the AlN content in the synthesis products. The results showed the mismatch of electrical resistance curves ρ(T) during the heating–cooling cycle for all ceramics compositions, which is associated with the variation in the length of the contact zone of conducting phases in range T = 800–1200 K. Three characteristic temperature regions are found: (I) from 300 to 800 K, when ρ monotonically increases with an increase in temperature; herewith, heating and cooling ρ(T) curves coincide completely; (II) the behavior of electrical resistance varies at T = 800–1200 K—its values depend strongly on the heat treatment mode of the sample; and (III) heating–cooling curves coincide completely at T > 1200 K.