The reagent Et 2 AlX/CH 2 N 2  in cyclopropanation of sterically hindered olefins, as well as oxygen- and nitrogen-containing unsaturated compounds

I. R. Ramazanov; A. V. Yaroslavova; N. R. Yaubasarov; E. N. Gil’manova; U. M. Dzhemilev

doi:10.1007/s11172-019-2638-5

The reagent Et₂AlX/CH₂N₂ in cyclopropanation of sterically hindered olefins, as well as oxygen- and nitrogen-containing unsaturated compounds

作者: Ramazanov I.¹, Yaroslavova A.¹, Yaubasarov N.¹, Gil’manova E.¹, Dzhemilev U.¹
隶属关系:
1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences
期: 卷 68, 编号 10 (2019)
页面: 1869-1873
栏目: Full Articles
URL: https://journals.rcsi.science/1066-5285/article/view/243499
DOI: https://doi.org/10.1007/s11172-019-2638-5
ID: 243499

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详细

A transition-metal-free method of cyclopropanation of sterically hindered olefins, substituted allylic alcohols, allylamines, and vinyl silyl ethers was developed using diazomethane in the presence of organic aluminum halides.