Synthesis and properties of carbosilane dendrimers with perfluorohexyl groups in the outer layer of the molecular structure
- 作者: Sheremetyeva N.1, Serenko O.2, Tatarinova E.1, Buzin M.2, Drozdov F.1, Elmanovich I.2,3, Gallyamov M.2,3, Muzafarov A.1,2
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隶属关系:
- N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Faculty of Physics, M. V. Lomonosov Moscow State University, Build. 2
- 期: 卷 67, 编号 8 (2018)
- 页面: 1440-1444
- 栏目: Article
- URL: https://journals.rcsi.science/1066-5285/article/view/242816
- DOI: https://doi.org/10.1007/s11172-018-2237-x
- ID: 242816
如何引用文章
详细
Branched perfluorohydrosiloxane with CF3CF2CF2C(CF3)2(CH2)3 groups at the silicon atom was synthesized by a sequence of chemical reactions. The resulting compound was used as a modifying agent for carbosilane dendrimers of the 3rd and 6th generations. Dendrimers with perfluorohexyl terminal groups in surface layer are characterized by a complex of physicochemical methods. It is demonstrated that due to the branching of perfluoroalkyl terminal groups, obtained carbosilane dendrimers are soluble in organic and inorganic media. Differences in the solubility of small and large dendrimers are caused by the formation of the outer fluoride shell of different densities.
作者简介
N. Sheremetyeva
N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences
Email: aziz@ispm.ru
俄罗斯联邦, 70 ul. Profsoyuznaya, Moscow, 117393
O. Serenko
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: aziz@ispm.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
E. Tatarinova
N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences
Email: aziz@ispm.ru
俄罗斯联邦, 70 ul. Profsoyuznaya, Moscow, 117393
M. Buzin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: aziz@ispm.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991
F. Drozdov
N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences
Email: aziz@ispm.ru
俄罗斯联邦, 70 ul. Profsoyuznaya, Moscow, 117393
I. Elmanovich
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Faculty of Physics, M. V. Lomonosov Moscow State University, Build. 2
Email: aziz@ispm.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991; 1 Leninskie Gory, Moscow, 119991
M. Gallyamov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; Faculty of Physics, M. V. Lomonosov Moscow State University, Build. 2
Email: aziz@ispm.ru
俄罗斯联邦, 28 ul. Vavilova, Moscow, 119991; 1 Leninskie Gory, Moscow, 119991
A. Muzafarov
N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: aziz@ispm.ru
俄罗斯联邦, 70 ul. Profsoyuznaya, Moscow, 117393; 28 ul. Vavilova, Moscow, 119991