Novel representatives of 16-membered aminomethylphosphines with alkyl substituents at nitrogen and their gold(I) complexes
- 作者: Musina E.1, Wittmann T.1, Lönnecke P.2, Hey-Hawkins E.2, Karasik A.1, Sinyashin O.1
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隶属关系:
- A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
- Institutе of Inorganic Chemistry, Leipzig University
- 期: 卷 67, 编号 2 (2018)
- 页面: 328-335
- 栏目: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/242197
- DOI: https://doi.org/10.1007/s11172-018-2078-7
- ID: 242197
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详细
Novel 1,9-diaza-3,7,11,15-tetraphosphacyclohexadecanes with alkyl, arylalkyl, or heteroarylalkyl substituents at the endocyclic nitrogen atoms were synthesized by condensation of 1,3-bis(phenylphosphino)propane, formaldehyde, and primary amines. The reactions are stereoselective and result in the isomer with the RSSR configuration of the phosphorus atoms as the major product. The 16-membered tetrakis(phosphine) ligands form stable neutral tetranuclear complexes with gold(I). In these complexes, the 16-membered cyclic ligands retain their free-state conformations and the configuration of the chiral phosphorus atoms.
作者简介
E. Musina
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: fesenkoTI@yandex.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088
T. Wittmann
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: fesenkoTI@yandex.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088
P. Lönnecke
Institutе of Inorganic Chemistry, Leipzig University
Email: fesenkoTI@yandex.ru
德国, Johannisallee 29, Leipzig, 04103
E. Hey-Hawkins
Institutе of Inorganic Chemistry, Leipzig University
Email: fesenkoTI@yandex.ru
德国, Johannisallee 29, Leipzig, 04103
A. Karasik
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: fesenkoTI@yandex.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088
O. Sinyashin
A.E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: fesenkoTI@yandex.ru
俄罗斯联邦, 8 ul. Arbuzova, Kazan, 420088