Specific features of “compensating” copolymerization of butyl acrylate with vinyl butyl ether in the presence of triethylboron
- Авторы: Semenycheva L.1, Matkivskaia Y.1, Valetova N.1, Chasova Y.1, Pegeev N.1, Eloyan A.1, Kursky Y.2, Moikin A.1
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Учреждения:
- N. I. Lobachevsky National Reseach State University of Nizhny Novgorod
- G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
- Выпуск: Том 66, № 9 (2017)
- Страницы: 1660-1664
- Раздел: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/241282
- DOI: https://doi.org/10.1007/s11172-017-1938-x
- ID: 241282
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Аннотация
Copolymerization of butyl acrylate with a large excess of boiling vinyl butyl ether was carried out in the presence of triethylborane. The analysis of the composition of the obtained product demonstrated that an alternating low-molecular-weight copolymer was predominantly formed. The formation of macromolecules occurred by both conventional and controlled radical polymerization (CRP), as evidenced by a bimodal molecular weight distribution. As conversion increased, the mode corresponding to the CRP mechanism shifted toward larger molecular masses. The relative activities of comonomers for the process initiated by triethylborane were calculated.
Об авторах
L. Semenycheva
N. I. Lobachevsky National Reseach State University of Nizhny Novgorod
Автор, ответственный за переписку.
Email: llsem@yandex.ru
Россия, 23 prosp. Gagarina, Nizhny Novgorod, 603950
Yu. Matkivskaia
N. I. Lobachevsky National Reseach State University of Nizhny Novgorod
Email: llsem@yandex.ru
Россия, 23 prosp. Gagarina, Nizhny Novgorod, 603950
N. Valetova
N. I. Lobachevsky National Reseach State University of Nizhny Novgorod
Email: llsem@yandex.ru
Россия, 23 prosp. Gagarina, Nizhny Novgorod, 603950
Yu. Chasova
N. I. Lobachevsky National Reseach State University of Nizhny Novgorod
Email: llsem@yandex.ru
Россия, 23 prosp. Gagarina, Nizhny Novgorod, 603950
N. Pegeev
N. I. Lobachevsky National Reseach State University of Nizhny Novgorod
Email: llsem@yandex.ru
Россия, 23 prosp. Gagarina, Nizhny Novgorod, 603950
A. Eloyan
N. I. Lobachevsky National Reseach State University of Nizhny Novgorod
Email: llsem@yandex.ru
Россия, 23 prosp. Gagarina, Nizhny Novgorod, 603950
Yu. Kursky
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: llsem@yandex.ru
Россия, 49 ul. Tropinina, Nizhny Novgorod, 603950
A. Moikin
N. I. Lobachevsky National Reseach State University of Nizhny Novgorod
Email: llsem@yandex.ru
Россия, 23 prosp. Gagarina, Nizhny Novgorod, 603950