Effect of promotion of nickel sulfide catalyst with silver on kinetics of decarbonilation of stearic acid
- Autores: Katsman E.1, Berenblyum A.1, Danyushevsky V.1, Karpov V.1, Kuznetsov P.1, Leont´eva S.1, Flid V.1
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Afiliações:
- MIREA – Russian Technological University, M. V. Lomonosov Institute of Fine Chemical Technology
- Edição: Volume 67, Nº 12 (2018)
- Páginas: 2224-2229
- Seção: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243220
- DOI: https://doi.org/10.1007/s11172-018-2359-1
- ID: 243220
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Resumo
The kinetics of liquid-phase decarbonylation of stearic acid in n-dodecane on γ-Al2O3 supported nickel sulfide catalyst promoted with silver was experimentally studied at 350 °C. The parameters of the reaction steps were determined and a structural kinetic model was developed. The model was compared with an earlier developed kinetic model for the unpromoted catalyst. It was suggested that an increased reaction selectivity in the presence of silver promoted catalyst was caused by a change in the composition of the adsorption complexes formed by the active sites of the catalyst. This change in the composition of the complexes is probably associated with an increase in the average size of the surface active particles of the catalyst.
Sobre autores
E. Katsman
MIREA – Russian Technological University, M. V. Lomonosov Institute of Fine Chemical Technology
Autor responsável pela correspondência
Email: katsman@aha.ru
Rússia, 86 prosp. Vernadskogo, Moscow, 119571
A. Berenblyum
MIREA – Russian Technological University, M. V. Lomonosov Institute of Fine Chemical Technology
Email: katsman@aha.ru
Rússia, 86 prosp. Vernadskogo, Moscow, 119571
V. Danyushevsky
MIREA – Russian Technological University, M. V. Lomonosov Institute of Fine Chemical Technology
Email: katsman@aha.ru
Rússia, 86 prosp. Vernadskogo, Moscow, 119571
V. Karpov
MIREA – Russian Technological University, M. V. Lomonosov Institute of Fine Chemical Technology
Email: katsman@aha.ru
Rússia, 86 prosp. Vernadskogo, Moscow, 119571
P. Kuznetsov
MIREA – Russian Technological University, M. V. Lomonosov Institute of Fine Chemical Technology
Email: katsman@aha.ru
Rússia, 86 prosp. Vernadskogo, Moscow, 119571
S. Leont´eva
MIREA – Russian Technological University, M. V. Lomonosov Institute of Fine Chemical Technology
Email: katsman@aha.ru
Rússia, 86 prosp. Vernadskogo, Moscow, 119571
V. Flid
MIREA – Russian Technological University, M. V. Lomonosov Institute of Fine Chemical Technology
Email: katsman@aha.ru
Rússia, 86 prosp. Vernadskogo, Moscow, 119571