Palladium-catalyzed synthesis of pyrimido[5’,4’:3,4]pyrrolo[1,2- f ]phenanthridine-12,14(11 H ,13 H )-diones and related compounds

M. A. Shevchenko; Y. N. Tkachenko; A. V. Astakhov; O. V. Khazipov; R. V. Tyurin; D. V. Pasyukov; V. A. Tafeenko; O. A. Kravchenko; V. M. Chernyshev

doi:10.1007/s11172-018-2277-2

Palladium-catalyzed synthesis of pyrimido[5’,4’:3,4]pyrrolo[1,2-f]phenanthridine-12,14(11H,13H)-diones and related compounds

Autores: Shevchenko M.A.¹, Tkachenko Y.N.², Astakhov A.V.¹, Khazipov O.V.¹, Tyurin R.V.¹, Pasyukov D.V.¹, Tafeenko V.A.³, Kravchenko O.A.¹, Chernyshev V.M.¹
Afiliações:
1. Platov South-Russian State Polytechnic University (NPI)
2. Southern Federal University
3. Lomonosov Moscow State University
Edição: Volume 67, Nº 9 (2018)
Páginas: 1684-1694
Seção: Article
URL: https://journals.rcsi.science/1066-5285/article/view/243005
DOI: https://doi.org/10.1007/s11172-018-2277-2
ID: 243005

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Resumo

Representatives of the new heterocyclic system, pyrimido[5’,4’:3,4]pyrrolo[1,2-f]phenanthridine, were obtained via the intramolecular C–H-arylation of 6-aryl-5-(2-bromophenyl) pyrrolo[3,4-d]pyrimidine-2,4-diones catalyzed by palladium complexes with N-heterocyclic carbene ligands (Pd/NHC).