N -β-Nitroxyethyl derivatives of 1,1’-[methylenebis(oxy)]bis(triaz-1-ene 2-oxides)

S. V. Nikitin; G. V. Pokhvisneva; T. V. Ternikova; P. B. Gordeev; I. M. Chistokhvalov; G. A. Smirnov; O. A. Luk’yanov

doi:10.1007/s11172-018-2238-9

N-β-Nitroxyethyl derivatives of 1,1’-[methylenebis(oxy)]bis(triaz-1-ene 2-oxides)

Autores: Nikitin S.¹, Pokhvisneva G.¹, Ternikova T.¹, Gordeev P.¹, Chistokhvalov I.², Smirnov G.¹, Luk’yanov O.¹
Afiliações:
1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2. D. I. Mendeleev University of Chemical Technology of Russia
Edição: Volume 67, Nº 8 (2018)
Páginas: 1445-1451
Seção: Article
URL: https://journals.rcsi.science/1066-5285/article/view/242819
DOI: https://doi.org/10.1007/s11172-018-2238-9
ID: 242819

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Synthetic procedures towards new N-β-hydroxyethyl- and N-β-bromoethylated 1,1’-[methyl enebis(oxy)]bis(triaz-1-ene 2-oxides) were developed. N-β-Nitroxyethyl[methylenebis(oxy)]- bis(triaz-1-ene 2-oxides) were first synthesized by nitration of N-β-hydroxyethyl derivatives and nucleophilic substitution of the bromine atom of N-β-bromoethyl derivatives. The first representative of a new class of energetic compounds, namely, (1-nitroxymethoxy)triaz-1-ene 2-oxide, was synthesized.