Paramagnetic CuII complexes with 1-(hetarylmethyl)silatranes
- Autores: Vakul’skaya T.I.1, Khutsishvili S.S.1, Pavlov D.V.1, Bolgova Y.I.1, Sterkhova I.V.1, Trofimova O.M.1
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Afiliações:
- A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
- Edição: Volume 66, Nº 12 (2017)
- Páginas: 2276-2282
- Seção: Full Article
- URL: https://journals.rcsi.science/1066-5285/article/view/241773
- DOI: https://doi.org/10.1007/s11172-017-2014-2
- ID: 241773
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Resumo
The structures of paramagnetic complexes CuCl2•L with L = HetCH2Si(OCH2CH2)3N [Het = pyrrol-1-yl (1), indol-1-yl (2), carbazol-9-yl (3), imidazole-1-yl (4), 3,5-dimethylpyrazol-1-yl (5), 1,2,4-triazol-1-yl (6), benzimidazol-1-yl (7), and 1,2,3-benzotriazol-1-yl (8)] were studied by the ESR and quantum chemical methods in terms of the density functional theory (DFT) approximation. The difference in structures of complexes CuCl2•1—CuCl2•8 is mainly determined by the nature of the five-membered heterocycle. The ESR spectra at room temperature are typical of the mononuclear complexes of CuII of axial symmetry with various types of distortions. In complexes CuCl2•1—CuCl2•3, narrow symmetric signals of zero-valent copper are recorded. These signals remain in the spectra for at least six months, which can characterize them as efficient stabilizing matrices of nanoparticles.
Sobre autores
T. Vakul’skaya
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Autor responsável pela correspondência
Email: vti@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
S. Khutsishvili
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: vti@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
D. Pavlov
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: vti@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
Yu. Bolgova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: vti@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
I. Sterkhova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: vti@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
O. Trofimova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
Email: vti@irioch.irk.ru
Rússia, 1 ul. Favorskogo, Irkutsk, 664033
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