Synthesis, structures, and thermal properties of terpolymers of propylene oxide, carbon dioxide, and cyclohexene oxide
- Authors: Nysenko Z.N.1, Said-Galiev E.E.2, Buzin M.I.2, Nikiforova G.G.2, Il’in M.M.2, Rusak V.V.1, Sakharov A.M.1
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Affiliations:
- N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Issue: Vol 68, No 11 (2019)
- Pages: 2119-2125
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243537
- DOI: https://doi.org/10.1007/s11172-019-2676-z
- ID: 243537
Cite item
Abstract
High molecular weight block terpolymers with different contents of polypropylene carbonate and cyclohexene carbonate units in the polymer chain were synthesized by the copolymerization of carbon dioxide, propylene oxide, and cyclohexene oxide. Zinc adipate was used as a catalyst. The terpolymerization products were characterized by 1H and 13C NMR spectroscopy, IR spectroscopy, GPC, DSC, and DMA methods. The influence of the reaction conditions on the composition, microstructure, and molecular-weight and thermal characteristics was studied.
About the authors
Z. N. Nysenko
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: nysenko@ioc.ac.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
E. E. Said-Galiev
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: ernest@ac.ineos.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
M. I. Buzin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: ernest@ac.ineos.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
G. G. Nikiforova
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: ernest@ac.ineos.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
M. M. Il’in
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: ernest@ac.ineos.ru
Russian Federation, 28 ul. Vavilova, Moscow, 119991
V. V. Rusak
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: ernest@ac.ineos.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991
A. M. Sakharov
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
Email: ernest@ac.ineos.ru
Russian Federation, 47 Leninsky prosp., Moscow, 119991