Email this article Polarity of para-disubstituted benzene derivatives: a correlation analysis of the substituent effect
- Authors: Kuznetsova O.V.1, Egorochkin A.N.1, Khamaletdinova N.M.1
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Affiliations:
- G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
- Issue: Vol 68, No 10 (2019)
- Pages: 1860-1865
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243497
- DOI: https://doi.org/10.1007/s11172-019-2636-7
- ID: 243497
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Abstract
The article is concerned with the influence of resonance donor substituents RD on the dipole moments μ of molecules 1,4-RDC6H4RA containing resonance acceptor groups RA (CF3, CN, COCH3, NO2 or COH) and grouped in five reaction (indicator) series. Generally, the μ values depend on the inductive, resonance, and polarizability effects of the substituents RD. Strengthening of the resonance acceptor properties of the RA groups leads to weaker conjugation between the substituents RD and the π-system.
About the authors
O. V. Kuznetsova
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: olga@iomc.ras.ru
Russian Federation, 49 ul. Tropinina, Nizhny Novgorod, 603950
A. N. Egorochkin
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: olga@iomc.ras.ru
Russian Federation, 49 ul. Tropinina, Nizhny Novgorod, 603950
N. M. Khamaletdinova
G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences
Email: olga@iomc.ras.ru
Russian Federation, 49 ul. Tropinina, Nizhny Novgorod, 603950
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