Enviar artigo por via de e-mail Crystal structure and two-level supramolecular organization of glycinium triiodide
- Autores: Shestimerova T.A.1, Bykov M.A.1, Wei Z.2, Dikarev E.V.2, Shevelkov A.V.1
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Afiliações:
- Department of Chemistry, M. V. Lomonosov Moscow State University
- Department of Chemistry, University at Albany
- Edição: Volume 68, Nº 8 (2019)
- Páginas: 1520-1524
- Seção: Full Article
- URL: https://journals.rcsi.science/1066-5285/article/view/243447
- DOI: https://doi.org/10.1007/s11172-019-2586-0
- ID: 243447
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Resumo
Glycinium triiodide was synthesized and its crystal structure was determined. The crystal structure consists of alternating asymmetric triiodide anions characterized by Raman spectroscopy and glycinium cations. The cations and anions form dimers (GlyH)2(I3)2via (N)H···O, (N)H···I, and (O)H···I hydrogen bonds. The dimers are further linked into chains by secondary I···I interactions between adjacent triiodide anions. The supramolecular structure of glycinium triiodide is discussed in comparison with polyiodides of various cations.
Sobre autores
T. Shestimerova
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: shev@inorg.chem.msu.ru
Rússia, Build. 3, 1 Leninskie Gory, Moscow, 119991
M. Bykov
Department of Chemistry, M. V. Lomonosov Moscow State University
Email: shev@inorg.chem.msu.ru
Rússia, Build. 3, 1 Leninskie Gory, Moscow, 119991
Z. Wei
Department of Chemistry, University at Albany
Email: shev@inorg.chem.msu.ru
Estados Unidos da América, Albany, New York, 12222
E. Dikarev
Department of Chemistry, University at Albany
Autor responsável pela correspondência
Email: edikarev@albany.edu
Estados Unidos da América, Albany, New York, 12222
A. Shevelkov
Department of Chemistry, M. V. Lomonosov Moscow State University
Autor responsável pela correspondência
Email: shev@inorg.chem.msu.ru
Rússia, Build. 3, 1 Leninskie Gory, Moscow, 119991
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