Email this article Synthesis of telehelic oligodimethylsiloxanes with 4-carboxypyrrolidone fragments: rheological and thermal properties
- Authors: Gorodov V.V.1,2, Bakirov A.V.1,3, Buzin M.I.2,4, Vasil´ev V.G.2, Shragin D.I.1,2, Myakushev V.D.1, Papkov V.S.2, Chvalun S.N.1,3, Muzafarov A.M.1,2
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Affiliations:
- N. S. Enikolopov Institute of Polymeric Materials, Russian Academy of Sciences
- A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Research Center “Kurchatov Institute,”
- V. I. Lenin Moscow Pedagogical State University
- Issue: Vol 67, No 12 (2018)
- Pages: 2282-2289
- Section: Full Articles
- URL: https://journals.rcsi.science/1066-5285/article/view/243232
- DOI: https://doi.org/10.1007/s11172-018-2371-5
- ID: 243232
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Abstract
Telehelic oligodimethylsiloxanes containing 4-carboxypyrrolidone fragments were synthesized by the reactions of oligodimethylsiloxanes bearing terminal 3-aminopropyl groups with itaconic acid. The thermal and rheological properties of the obtained polymers were studied. The activation energies of viscous flow of the oligomers obtained and the previously synthesized oligodimethylsiloxanes containing terminal fragments of undecenoic or benzoic acid are compared.
About the authors
V. V. Gorodov
N. S. Enikolopov Institute of Polymeric Materials, Russian Academy of Sciences; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Author for correspondence.
Email: gorodov.v.v@gmail.com
Russian Federation, 70 ul. Profsoyuznaya, Moscow, 117393; 28 ul. Vavilova, Moscow, 119991
A. V. Bakirov
N. S. Enikolopov Institute of Polymeric Materials, Russian Academy of Sciences; Research Center “Kurchatov Institute,”
Email: gorodov.v.v@gmail.com
Russian Federation, 70 ul. Profsoyuznaya, Moscow, 117393; 1 pl. Akad. Kurchatova, Moscow, 123182
M. I. Buzin
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences; V. I. Lenin Moscow Pedagogical State University
Email: gorodov.v.v@gmail.com
Russian Federation, 28 ul. Vavilova, Moscow, 119991; 1 ul. Malaya Pirogovskaya, Moscow, 119992
V. G. Vasil´ev
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: gorodov.v.v@gmail.com
Russian Federation, 28 ul. Vavilova, Moscow, 119991
D. I. Shragin
N. S. Enikolopov Institute of Polymeric Materials, Russian Academy of Sciences; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: gorodov.v.v@gmail.com
Russian Federation, 70 ul. Profsoyuznaya, Moscow, 117393; 28 ul. Vavilova, Moscow, 119991
V. D. Myakushev
N. S. Enikolopov Institute of Polymeric Materials, Russian Academy of Sciences
Email: gorodov.v.v@gmail.com
Russian Federation, 70 ul. Profsoyuznaya, Moscow, 117393
V. S. Papkov
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: gorodov.v.v@gmail.com
Russian Federation, 28 ul. Vavilova, Moscow, 119991
S. N. Chvalun
N. S. Enikolopov Institute of Polymeric Materials, Russian Academy of Sciences; Research Center “Kurchatov Institute,”
Email: gorodov.v.v@gmail.com
Russian Federation, 70 ul. Profsoyuznaya, Moscow, 117393; 1 pl. Akad. Kurchatova, Moscow, 123182
A. M. Muzafarov
N. S. Enikolopov Institute of Polymeric Materials, Russian Academy of Sciences; A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: gorodov.v.v@gmail.com
Russian Federation, 70 ul. Profsoyuznaya, Moscow, 117393; 28 ul. Vavilova, Moscow, 119991
